Applied Physics Letters publishes a research paper by PhD student Cuiqian Yu on strong four-phonon scattering in monolayer and hydrogenated bilayer BAs with horizontal mirror symmetry
The Boltzmann transport equation based on third-order anharmonic scattering is widely used to predict the thermal conductivity of material lattices, often obtaining results that agree with experimental measurements. Recently, the important role of high-order anharmonic phonon–phonon interactions has been revealed in several materials, such as cubic boron arsenide (BAs), in which the wide phononic energy gap is found to be a critical factor causing the importance of four-phonon scattering. In this work, by solving the Boltzmann transport equation, we show that the four-phonon scattering has a significant impact on the thermal transport in honeycomb structured monolayer BAs (m-BAs) and its hydrogenated bilayer counterparts (bi-BAs) [Fig. 1(d)]. The lattice thermal conductivity (κL) values of all these structures are reduced after considering four-phonon scattering.